Synthesis of 2-Chloromethyl-1-(p-vinylphenyl)cyclopropane and Its Copolymerization with Styrene
| Autor: | A. M. Aliyeva, Ts. D. Gulverdashvili, K. G. Guliyev, D. B. Tagiyev, G. Z. Ponomareva, A. I. Sadygova |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) General Chemical Engineering 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Ring (chemistry) 01 natural sciences 0104 chemical sciences Styrene Cyclopropane chemistry.chemical_compound Monomer chemistry Photosensitivity Polymer chemistry Copolymer Moiety 0210 nano-technology |
| Zdroj: | Russian Journal of Applied Chemistry. 91:304-309 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427218020209 |
| Popis: | A new polyfunctional monomer, 2-chloromethyl-1-(p-vinylphenyl)cyclopropane, was synthesized, and its radical copolymerization with styrene was performed. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The photochemical cross-linking of the synthesized copolymer containing photosensitive groups (cyclopropane ring, chlorinated organic moiety) was studied. The copolymer exhibits relatively high photosensitivity (54 cm2 J–1) and can be used as a photosensitive base of negative photoresists. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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