Mechanism of carbon-nitrogen bond cleavage during amylamine hydrodenitrogenation over a sulphided NiMo/Al2O3 catalyst

Autor:	M. Breysse, J.L. Portefaix, M. Cattenot, M. Guerriche
Rok vydání:	1991
Předmět:	Reaction mechanism Hydrogen Inorganic chemistry chemistry.chemical_element General Chemistry Photochemistry Heterogeneous catalysis Catalysis chemistry.chemical_compound chemistry Carbon–nitrogen bond Hydrodenitrogenation Carbon Bond cleavage
Zdroj:	Catalysis Letters. 9:127-132
ISSN:	1572-879X 1011-372X
Popis:	By comparison of the hydrodenitrogenation rate of amylamine with those of neopentylamine and tert-amylamine over a conventional catalyst, it was evidenced that the hydrogen atoms of the carbon in the β position with respect to the nitrogen atom participate in the C-N bond cleavage. A detailed mechanism including the interaction with the catalyst is proposed for this reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b13b1d80f2541c9de5ada525af50930c https://doi.org/10.1007/bf00769091 Zobrazit plný text záznamu Full text from SpringerLink