Resolution of 5- and 6-Membered P-Heterocycles: Racemic and Optically Active Platinum(II)-3-Phospholene Complexes

Autor:	Elemér Fogassy, György Keglevich, András Fekete, Tamara Kovács, Péter Bagi, Andrea Laki
Rok vydání:	2013
Předmět:	Inorganic Chemistry chemistry Reaction sequence Phosphorus Organic Chemistry Resolution (electron density) chemistry.chemical_element Platinum complex Organic chemistry Optically active Platinum Biochemistry Catalysis
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 188:36-38
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426507.2012.743545
Popis:	Methods were developed for the resolution of several five- and six-membered phosphorus heterocycles (1c-e, 2, 4). It was investigated if the optical activity is preserved during the 1a→2→3→4 reaction sequence. Racemic and optically active 1b-e 3-phospholene 1-oxides were converted to the corresponding platinum-complexes (10b-e), which are potential catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b1378181d9be81cd767c6607c82e9343 https://doi.org/10.1080/10426507.2012.743545 Zobrazit plný text záznamu