ChemInform Abstract: Tandem Pummerer Diels-Alder Sequence for the Preparation of α- Thio Substituted Naphthalene Derivatives

Autor:	J. E. Cochran, Albert Padwa
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Tandem Pummerer rearrangement fungi Diels alder Thio Sulfoxide Sequence (biology) General Medicine Medicinal chemistry Cycloaddition Naphthalene
Zdroj:	ChemInform. 26
ISSN:	0931-7597
DOI:	10.1002/chin.199536121
Popis:	The α-thiocarbocation generated from the Pummerer reaction of an o -benzoyl substituted sulfoxide is intercepted by the adjacent keto group to produce an α-thio-isobenzofuran as a transient intermediate which undergoes a subsequent Diels-Alder cycloaddition with added dienophiles.
Databáze:	OpenAIRE
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