Negative Ion Zero Electron Kinetic Energy Spectroscopy of I-.cntdot.CH3I

Autor:	Donna M. Cyr, Caroline C. Arnold, Mark A. Johnson, Daniel M. Neumark
Rok vydání:	1995
Předmět:	Chemistry Photoemission spectroscopy General Engineering Electron Kinetic energy Electron spectroscopy Ion symbols.namesake Excited state symbols Physical and Theoretical Chemistry van der Waals force Atomic physics Spectroscopy
Zdroj:	The Journal of Physical Chemistry. 99:1633-1636
ISSN:	1541-5740 0022-3654
Popis:	The negative ion zero electron kinetic energy (ZEKE) spectrum of I[sup [minus]]-CH[sub 3]I is presented and discussed. In addition to the high-frequency vibrational structure previously seen in the photoelectron spectrum (PES) of I[sup [minus]]CH[sub 3]I, the ZEKE spectrum reveals low-frequency vibrational structure due to excitation in two van der Waals modes in the ground (X) state of the neutral I-CH[sub 3]I complex. Of the two other excited states of the neutral complex, the I state is not distinctly observed, and no vibrational structure due to van der Waals motion is observed for the II state. 22 refs., 3 figs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b107d9e7746508f740fb4b3c37190638 https://doi.org/10.1021/j100006a002 Zobrazit plný text záznamu