Self-propagating high-temperature synthesis of titanium nitride with the participation of ammonium chloride
| Autor: | Yu. N. Barinov, V. V. Zakorzhevskii, I. D. Kovalev |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010302 applied physics
Materials science General Chemical Engineering Metallurgy Metals and Alloys Self-propagating high-temperature synthesis chemistry.chemical_element Sintering 02 engineering and technology Nitride 021001 nanoscience & nanotechnology 01 natural sciences Nitrogen Titanium nitride Inorganic Chemistry chemistry.chemical_compound chemistry Chemical engineering Specific surface area 0103 physical sciences Materials Chemistry 0210 nano-technology Tin Titanium |
| Zdroj: | Inorganic Materials. 53:278-286 |
| ISSN: | 1608-3172 0020-1685 |
| DOI: | 10.1134/s002016851703013x |
| Popis: | We have studied the combustion of titanium in nitrogen in the presence of ammonium chloride. It has been shown that the use of NH4Cl in the self-propagating high-temperature synthesis of TiN considerably reduces the combustion temperature, prevents sintering of the synthesized titanium nitride particles, and increases their specific surface area. The synthesis products have the form of nanostructured titanium nitride particles which reproduce the shape of the starting titanium particles but consist of equiaxed titanium nitride grains ranging in size from 50 to 500 nm. We have obtained nanostructured titanium nitride powders ranging in specific surface area up to 80 m2/g. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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