Macrocyclic polythiaethers as solvent extraction reagents—II

Autor:	H. Meider, D. Sevdić
Rok vydání:	1977
Předmět:	Polymers and Plastics Inorganic chemistry Ionic bonding chemistry.chemical_element Chloride Mercury (element) symbols.namesake Perchlorate chemistry.chemical_compound chemistry Reagent Materials Chemistry symbols medicine Raman spectroscopy Solvent extraction Equilibrium constant Nuclear chemistry medicine.drug
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 39:1409-1413
ISSN:	0022-1902
DOI:	10.1016/0022-1902(77)80307-2
Popis:	Tetradentate and octadentate sulfur containing macrocyclic polythiaethers 1,4,8,11-tetrathiacyclotetradecane (TTP) and 1,4,8,11,15,18,22,25-octathiacyclooctacosane (OTO) have been used for mercury(II) extraction from chloride and perchlorate solutions. HgCl2L and ionic HgL2+ complexes form in the organic phase (L = TTP or OTO respectively). The equilibrium constants which characterize the extraction were calculated. The complexes Hg(TTP)Cl2, Hg2(TTP)Cl4·4 H2O, [Hg(TTP)](ClO4)2·2 H2O, [Hg(OTO)](ClO4)2·2 H2O and Hg4(OTO)Cl8·4 H2O have been prepared and characterized. IR and Raman spectra have been recorded, the characteristic frequencies of the vibrations ClHgCl, SHgS and CSC have been assigned.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b0c78e90a1042518b4df5daddfcbdcbb https://doi.org/10.1016/0022-1902(77)80307-2 Zobrazit plný text záznamu