X-ray diffraction study of [Ru(NH3)5Cl][ReCl6] and [Ru(NH3)5Cl]2[ReCl6]Cl2 and their thermolysis products. Crystal-chemical analysis of the Ru-Re system

Autor:	K. V. Yusenko, S. A. Martynova, I. V. Korol’kov, I. A. Baidina, Sergey V. Korenev
Rok vydání:	2009
Předmět:	Crystal chemistry Chemistry Thermal decomposition chemistry.chemical_element Rhenium Ruthenium Inorganic Chemistry Crystallography X-ray crystallography Materials Chemistry Physical and Theoretical Chemistry Isostructural Bimetallic strip Solid solution
Zdroj:	Journal of Structural Chemistry. 50:120-126
ISSN:	1573-8779 0022-4766
DOI:	10.1007/s10947-009-0016-0
Popis:	Binary complex salts [Ru(NH3)5Cl][ReCl6] and [Ru(NH3)5Cl]2[ReCl6]Cl2 were synthesized and characterized. An X-ray diffraction analysis showed that they were isostructural with the previously obtained isoformula salts [Rh(NH3)5Cl][OsCl6] and [Ir(NH3)5Cl]2[PtCl6]Cl2, respectively. Thermolysis of these compounds under hydrogen and helium was studied. According to X-ray phase analysis data, bimetallic solid solutions Ru0.67Re0.33 and Ru0.50Re0.50 were the final products of thermolysis. Their unit cell parameters correspond to the characteristics of alloys with similar compositions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b0c5084de6cc9c9402ded0ee727b0307 https://doi.org/10.1007/s10947-009-0016-0 Zobrazit plný text záznamu Plný text ve formátu PDF