Catalyst- and Solvent-Free Synthesis of α-Amino Polyfluoroalkylphosphonates from Bis(fluoroalkyl) Phosphonates and Aldimines

Autor: Svetlana N. Arbuzova, S. I. Verkhoturova, S. V. Zinchenko, Nikita A. Kolyvanov, Nina K. Gusarova, Boris A. Trofimov, T. I. Kazantseva
Rok vydání: 2020
Předmět:
Zdroj: Synthesis. 52:1531-1540
ISSN: 1437-210X
0039-7881
DOI: 10.1055/s-0039-1691599
Popis: The catalyst- and solvent-free reaction between bis(fluoroalkyl) phosphonates and aldimines occurs under mild conditions (20–22 °C, 0.25–4 h) to afford a new family of α-amino polyfluoroalkylphosphonates in up to quantitative yields.
Databáze: OpenAIRE