A new crystalline framework formed from 1,4-bis(4-pyridylmethyl)piperazine and Cd(NO3)2: Interpenetrating molecular ladders from T-shaped building blocks
| Autor: | Shi-Kai Liang, Yang Meng, Chi Ma, Ying-Ying Li, En-Jun Gao, Fu-Chen Zhao, Jie Zhang, Ling-Feng Li, Lu Wang |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
Stereochemistry
Coordination polymer Infrared spectroscopy Bridging ligand 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound Piperazine Crystallography chemistry visual_art Pyridine Materials Chemistry visual_art.visual_art_medium Cadmium nitrate Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Journal of Structural Chemistry. 56:1619-1622 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s0022476615080259 |
| Popis: | Coordination of a pyridine-based bridging ligand, 4-bpmp, with cadmium nitrate afforded an infinite ladder-type complex {[Cd(4-bpmp)2(H2O)Cl2]} n (A) (4-bpmp = 1,4-bis(4-pyridylmethyl)piperazine) containing T-shaped building blocks. IR spectra, elemental analysis, and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure of complex A. Inclined interpenetration of infinite ladders was observed in the solid structure. The combined work demonstrates the ability of bipyridyl coordination polymer leads to a novel metal complex with impressive structural motif. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|