Synthesis of M0(η2-dppf)2 (M  Pd, Pt; dppf  Fe(C5H4PPh2)2) and their reactions with Fe3(μ3-S)2(CO)9 and elemental sulfur

Autor:	Siu-Choon Ng, Pauline M. N. Low, Zhi Gang Fang, T. S. Andy Hor
Rok vydání:	1994
Předmět:	Inorganic Chemistry Chemistry Organic Chemistry Inorganic chemistry Materials Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Platinum Biochemistry Sulfur Medicinal chemistry Palladium
Zdroj:	Journal of Organometallic Chemistry. 483:17-20
ISSN:	0022-328X
DOI:	10.1016/0022-328x(94)87141-8
Popis:	Reduction of MCl2(η2-dppf) with NaBH4 gives M(η2-dppf)2 (M  Pt, 1, Pd, 2). Oxidation of 1 or 2 with S8 gives the tetrasulfido complex M(η2-S4)(η2-dppf). Addition of 1 or 2 to Fe3 (μ3-S)2(CO)9 results in the heterometallic complex (CO)6Fe2(μ3-S)2 M(η2-dppf) (M  Pt, 5; Pd, 6) and two substitution side products Fe3(μ3-S)2(CO)7(μ-dppf) (7) and [Fe3(μ3-S) 2(CO)8]2(μ-dppf) (8).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b0a65862febf70108c8ec52d17c9ffaa https://doi.org/10.1016/0022-328x(94)87141-8 Zobrazit plný text záznamu