Double complex salts with [Ru(NH3)5Cl]2+ cation and [OsCl6]2− anion: Synthesis and properties. Crystal structure of [Ru(NH3)5Cl]2[OsCl6]Cl2

Autor:	K. V. Yusenko, Sergey V. Korenev, I. V. Korol’kov, S. A. Martynova
Rok vydání:	2010
Předmět:	Diffraction Hydrogen Materials Science (miscellaneous) Thermal decomposition chemistry.chemical_element Crystal structure Inorganic Chemistry Metal Crystallography chemistry visual_art visual_art.visual_art_medium Physical and Theoretical Chemistry Isostructural Phase diagram Solid solution
Zdroj:	Russian Journal of Inorganic Chemistry. 55:1347-1351
ISSN:	1531-8613 0036-0236
DOI:	10.1134/s0036023610090032
Popis:	Double complex salts [Ru(NH3)5Cl][OsCl6] and [Ru(NH3)5Cl]2[OsCl6]Cl2 were prepared and characterized. An X-ray diffraction study showed that [Ru(NH3)5Cl][OsCl6] is isostructural to the previously synthesized [Rh(NH3)5Cl][OsCl6]. The structure of [Ru(NH3)5Cl]2[OsCl6]Cl2 was solved by X-ray diffraction (a = 11.1849(8) A, b = 7.9528(6) A, c = 13.4122(9) A; β = 99.765(2)°; V= 1175.75 A3; space group C2/m; Z = 2). Thermolysis of the compounds under hydrogen and helium was studied. According to X-ray diffraction, nanosized metallic powders of the corresponding alloys are formed as the final products of thermolysis. The compositions of the obtained solid solutions are consistent with the phase diagram of the Ru-Os system.
Databáze:	OpenAIRE
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