Alkali metal⋯methyl short contacts in aluminates: more than agostic interactions
| Autor: | Jesús Damián, Christian Rentero, Jorge Echeverría, Marta E. G. Mosquera |
|---|---|
| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Faraday Discussions. |
| ISSN: | 1364-5498 1359-6640 |
| DOI: | 10.1039/d2fd00144f |
| Popis: | Short contacts between alkali metal cations and methyl groups in aluminates, traditionally considered agostic interactions, can be rationalized in terms of an electron-rich carbon atom and its interaction with the cation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|