ELEMENTAL SULFUR REACTIONS WITH 2-PICOLINE

Autor:	Zygmunt Warnke, Edward Gleich
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Sulfide Organic Chemistry chemistry.chemical_element Mass spectrometry Biochemistry Sulfur Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Propane Field desorption Pyridine Mass spectrum Electron ionization
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 53:211-222
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509008038028
Popis:	A study of the reaction of the elemental sulfur with 2-picoline is reported. The process was carried out at the boiling point of the 2-picoline under argon. After removing unreacted solids, the reaction products were identified by means of LC. GC and GC-MS. The following products have been identified by mass spectrometry: 1,2-di/2-pyridyl/-ethane. 1,2-di/2-pyridyl/-ethene. 2-methyl-x-[/2-pyridyl/methyl]pyridines, 2-mercapto-methyl-[x/2-pyridyl/methyl]-pyridines, l-mercapto-1,2-di/2-pyridyl/-ethane, 5,6-di/2-pyridyl/-5H-cyclopenta-[b]pyridine, 5,6-di/2-pyridyl/-7H-cyclopenta[b]pyridine, 1,2,3-tri/2-pyridyl/-propane. 1,2-di/2-pyridyl/-1-[x-/2-methyl/-pyridyl]-ethane, 5,6-di/2-pyridyl/-7-[/2-pyridyl/methyl]-7H-cyclopenta[b]pyridine, 5,6-di/2-pyridyl/-5-[/2-pyridyl/-methyl]-5H-cyclopenta-[b]pyridine. Di{7-[5,6-di/2-pyridyl/-7H-cyclopenta[b]pyridyl]} sulfide and di(7-[5,6-di/2-pyridyl/-7H-cyclopentalblpyridyl]} disulfide.
Databáze:	OpenAIRE
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