Transport through Microemulsion-Based Organo-gels
| Autor: | Feyza Atadinc, Naz Zeynep Atay-Guneyman, Yucel Kozluca |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
Aqueous solution
Chemistry Ligand Metal ions in aqueous solution Inorganic chemistry Murexide Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials Metal chemistry.chemical_compound Colloid and Surface Chemistry Reaction rate constant visual_art Phase (matter) visual_art.visual_art_medium Microemulsion |
| Zdroj: | Journal of Colloid and Interface Science. 169:246-248 |
| ISSN: | 0021-9797 |
| Popis: | An AOT-stabilized water-in-oil (w/o) microemulsion, containing metal ions in its aqueous region, can be set into a hard, stable organo-gel upon addition of gelatin to the solution. When this microemulsion-based organo-gel is in contact with a w/o microemulsion, both the microemulsion solution and the organo-gel remain intact. If the water droplets of the w/o microemulsion contain a ligand, such as murexide, a communication between the water droplets of the organo-gel and those of the w/o microemulsion is observed in the form of a metal ion/ligand complexation reaction. The metal ions, solubilized within the aqueous region of the organo-gel, are transported to the dispersed phase of the microemulsion in a slow step. This is then followed by the rapid metal ion/murexide complexation reaction. A similar mechanism is observed if the dispersed phase is changed to glycerol + water mixtures. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect