Supramolecular Bromoantimonate(V) Polybromide (2,6-BrPyH)3[SbBr6]{(Br2)Br} · 2H2O: Specific Features of Halogen···Halogen Contacts in the Crystal Structure

Autor:	M. A. Bondarenko, Vladimir P. Fedin, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin
Rok vydání:	2020
Předmět:	chemistry.chemical_classification Halogen bond Structure analysis Chemistry General Chemical Engineering Supramolecular chemistry Solid-state chemistry.chemical_element General Chemistry Crystal structure Crystallography Antimony Halogen Non-covalent interactions
Zdroj:	Russian Journal of Coordination Chemistry. 46:302-307
ISSN:	1608-3318 1070-3284
Popis:	The reaction of a solution of Sb2O3 in HBr in the presence of Br2 with a solution of 2,6-dibromopyridine (2,6-BrPy) in HBr affords supramolecular bromoantimonate polybromide (2,6-BrPy)3[SbBr6]-{(Br2)Br} · 2H2O (I). The structure of compound I is determined by X-ray structure analysis (СIF file CCDC no. 1962867). The energies of noncovalent Br···Br interactions in the solid state are estimated by quantum-chemical calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b03c98a7219d5f516d942db35ef25686 https://doi.org/10.1134/s1070328420040016 Zobrazit plný text záznamu Full text from SpringerLink