Synthesis, crystal structures and spectroscopic properties of dichloroethylphenyltin(IV) and its phenanthroline adduct

Autor:	José Sordo, María S. García-Tasende, Agustín Sánchez, María J. Vidarte, Carmen Taboada, Javier Ellena, José S. Casas, Eduardo E. Castellano
Rok vydání:	2003
Předmět:	Chloroform Phenanthroline Intermolecular force Inorganic chemistry General Chemistry Crystal structure Carbon-13 NMR Adduct Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Octahedron Proton NMR
Zdroj:	Applied Organometallic Chemistry. 17:940-944
ISSN:	0268-2605
Popis:	The reaction of dichloroethylphenyltin(IV), Ph(Et)SnCl2, with phenanthroline monohydrate (phen·H2O) in chloroform, in 1:1 mole ratio, afforded [Ph(Et)SnCl2(phen)]. The crystal structures of dichloroethylphenyltin(IV) and its phenanthroline adduct were studied by X-ray diffraction. In Ph(Et)SnCl2 the tin atom is in a distorted tetrahedral environment, the distortion probably being imposed by weak intermolecular Sn· · ·Cl interactions. In [Ph(Et)SnCl2(phen)] the tin atom is in an octahedral trans-C2, cis-Cl2, N2 environment and weak intermolecular C–H· · ·Cl interactions connect the molecules throughout the lattice. Spectroscopic studies in solution (1H, 13C and 119Sn NMR) were also carried out; the 1H and 13C NMR data in dimethylsulfoxide suggest that [Ph(Et)SnCl2(phen)] remains at least partially undissociated in this solvent. Copyright © 2003 John Wiley & Sons, Ltd.
Databáze:	OpenAIRE
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