Synthesis, structures and polyphenol oxidase activities of dicopper and dicobalt complexes

Autor:	Yong Zhang, Chang Lin Liu, Zhan Ru Liao, Dongfeng Li, Xiang Gao Meng
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Reaction rate constant Pyrogallol Chemistry Materials Chemistry Organic chemistry Dimethylformamide Ether Crystal structure Physical and Theoretical Chemistry Medicinal chemistry Polyphenol oxidase
Zdroj:	Journal of Coordination Chemistry. 62:876-885
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958970802389755
Popis:	Two dinuclear complexes [M2(EGTB)(NO3)2(DMF)2](NO3)2 · 2DMF (M = Cu, 1; Co, 2) were synthesized and structurally characterized, EGTB is N,N,N′,N′-tetrakis (2-benzimidazolylmethyl)-1,4-diethylene amino glycol ether, and DMF is dimethylformamide. The polyphenol oxidase (PPO) activities of 1 and 2 on pyrogallol oxidation have been investigated, showing that the rate constants k cat increase with increases of reaction temperatures and pH.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b02dc0c556a50d1e5252cf13236efb54 https://doi.org/10.1080/00958970802389755 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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