Phencyclone Diels-Alder adducts as a new crystalline host. Role of CH···π and CH···O interactions

Autor: Eri Sugiyama, Kazunobu Harano, Koji Setoguchi, Akiko Harada, Masashi Eto
Rok vydání: 1998
Předmět:
Zdroj: Tetrahedron Letters. 39:9751-9754
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02283-7
Popis: A series of crystalline host compounds, which have a bicyclo[2.2.1]heptene-7-one system, has been synthesized and their inclusion behavior has been investigated. The cycloadduct of phencyclone and N-naphthylmaleimide forms a 1:1 crystalline inclusion complex with 2-butanone. The crystal structure indicates the presence of weak lattice forces supported by CH···π and CH···O interactions.
Databáze: OpenAIRE