Chemical Structure Determination of Lantanides’ Coordination Compounds on the Basis of Their Absorption Spectra

Autor:	N. K. Davidenko, K. B. Yatsimirsky, N. A. Kostromina, T. V. Ternovaya
Rok vydání:	1964
Předmět:	chemistry.chemical_classification Materials science chemistry Absorption spectroscopy Basis (linear algebra) Chemical bond Chemical physics Chemical structure Rare earth Ionic bonding Molecular physics Coordination complex Ion
Zdroj:	Proceedings of the 8th International Conference on Coordination Chemistry ISBN: 9783709136522
DOI:	10.1007/978-3-7091-3650-8_30
Popis:	Heretofore the majority of investigators considered the chemical bond in coordination compounds of the rare earths elements to be of ionic nature. Within the last years, however, many arguments have been submitted in favour of a partial covalency of the formed bonds. One of the reasons points out at the impossibility to deduce thermodynamical characteristics of the complexes on the mere basis of the ions charges and radii. An ample information on the geometry and chemical structure of the rare earth coordination compounds may be obtained on the basis of their absorption spectra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b006e2db7a23ce13de64dcb196886e76 https://doi.org/10.1007/978-3-7091-3650-8_30 Zobrazit plný text záznamu