Alkoxy, thiophenolato and amido complexes of molybdenum tris-(3,5-dimethylpyrazolyl)borato nitrosyl acetate and benzoate, and the X-ray crystal structure of Mo{HB(3,5-Me2C3HN2)3}(NO)(NHPh)(OCOMe)·2CHCl3

Autor:	Anthony J. Edwards, Andrzej Wlodarczyk, Jon A. McCleverty
Rok vydání:	1988
Předmět:	Tris Denticity Stereochemistry chemistry.chemical_element Infrared spectroscopy Crystal structure Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Molybdenum Alkoxide Materials Chemistry Alkoxy group Carboxylate Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 7:103-115
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)80455-6
Popis:	The complexes MoL*(NO)(OR)(OCOR′) (L* = HB(3,5-Me 2 C 3 HN 2 ) 3 ; R = Me, Et, Pr n , Pr i ; R′= Me, Ph: R = CH 2 CH 2 OH, OH; R′= Ph: R = Ph, C 6 H 4 OMe- p ; R′= Me, Ph: R = C 6 H 4 Me-p; R′= Me), MoL*(NO)(SPh)(OCOR′) (R = Me or Ph) and MoL*(NO)(NHR)(OCOR′) (R = Me, Et, Ph; R′ = Me, Ph) were prepared by reaction of MoL*(NO)I(OR), MoL*(NO)I(SPh) and MoL*(NO)I(NHR) with AgOCOMe or AgOCOPh. The IR spectra of these complexes indicated that the carboxylate groups are monodentate and this was confirmed by a single crystal X-ray structural determination of MoL*(NO)(NHPh)(OCOMe).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::afe132fa8b9b266d5fce70470e1c5f72 https://doi.org/10.1016/s0277-5387(00)80455-6 Zobrazit plný text záznamu