Double Michael reaction of Wieland-Miescher ketone

Autor: Tetsuji Okamoto, Nobuyuki Harada, Hisahiro Hagiwara, Hisashi Uda
Rok vydání: 1995
Předmět:
Zdroj: Tetrahedron. 51:9891-9898
ISSN: 0040-4020
Popis: Enolate of Wieland-Miescher ketone 1 has reacted with methyl acrylate to give methyl (1S*,2S*,4R*,6S*)-6-methyltricyclo[6.2.2.0 1,6]-dodecan-7, 12-dion-2-carboxylate 5 whose structure has been determined by X-ray crystallography after transformation of 5 into sultamamide 8a.
Databáze: OpenAIRE