Kinetic study of the reaction of OH radicals with nitrosyl chloride as a possible source of ClOH

Autor:	J. L. Jourdain, G. Laverdet, G. Le Bras, Gilles Poulet
Rok vydání:	1981
Předmět:	chemistry.chemical_compound Primary (chemistry) chemistry Radical General Physics and Astronomy Absolute rate Nitrosyl chloride Physical and Theoretical Chemistry Photochemistry Kinetic energy Mass spectrometric
Zdroj:	Chemical Physics Letters. 81:573-577
ISSN:	0009-2614
DOI:	10.1016/0009-2614(81)80466-6
Popis:	The reaction of OH with NOCl has been studied using the discharge flow reaction-EPR technique. The absolute rate constant is k1 = (4.3±0.4)× 10−13 cm3 molecule−1 s−1 at 298 K. A mass spectrometric investigation of the products shows that this reaction occurs via two primary steps, OH + NOCl → NO + ClOH(1a) and OH + NOCl → HONO + Cl (1b) with k1a =k1b.
Databáze:	OpenAIRE
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