EXCHANGE OF N15H3 BETWEEN SOLVENT AND LIGANDS IN COMPLEX METAL AMMINES1
| Autor: | John R. Sutter, John P. Hunt |
|---|---|
| Rok vydání: | 1960 |
| Předmět: |
Chemistry
Inorganic chemistry Analytical chemistry chemistry.chemical_element General Chemistry Mass spectrometry Biochemistry Mass spectrometric Nitrogen Catalysis Metal Solvent Ammonia chemistry.chemical_compound Colloid and Surface Chemistry Nickel compounds visual_art visual_art.visual_art_medium |
| Zdroj: | Journal of the American Chemical Society. 82:6420-6420 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | A turbulent flow apparatus was used for qualitative study of the exchange of N/sup 15/H/sub 3/ between solvent and ligands in complex metal ammines. The N/sup 15/-enriched liquid NH/sub 3/ was mixed in approximately O.O1 sec with an unenriched solution of the metal salt in liquid NH/sub 3/ below --35 deg C, the mixture quenched and then subjected to mass spectrometric analysis of the nitrogen from the solvent. Half times for the exchange reactions are presented for the salts Cu(NH/sub 3/)/sub 4/(NO/sub 3/)/sub 2/, Ni(NH/sub 3/)/sub 6/(NO i)/sub 2/, AlI/sub 3/, Al(NH/sub 3/)/sub 6/I/sub 3/, and Ag(NH/sub 3/)/ sub 2/NO/sub 3/; all of the half t imes are on the order of 1 sec or less. (D.L.C.) |
| Databáze: | OpenAIRE |
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