Synthesis and Characterization of Low Molecular Weight Organogelators Derived from Amide Derivatives of N-acetylglycine

Autor: Firdous Imran Ali Firdous Imran Ali, Rabel Shaikh Rabel Shaikh, Ahmed Bari Ahmed Bari, Umair Ahmad Khan Umair Ahmad Khan, Shoaib Muhammad and Imran Ali Hashmi Shoaib Muhammad and Imran Ali Hashmi
Rok vydání: 2019
Předmět:
Zdroj: Journal of the chemical society of pakistan. 41:99-99
ISSN: 0253-5106
DOI: 10.52568/000720/jcsp/41.01.2019
Popis: Six new N-acetylglycine amides and bisamides were prepared by reacting N-acetylglycine with different isocyanates including, hexamethylene diisocyanate, bis(4-isocyanatophenyl)methane, toluene 2,4-diisocyanate, 1,3-bis(2-isocyanatopropan-2-yl)benzene, phenyl isocyanate and 2-naphthyl isocyanate to furnish amides 1-6. The gelation ability of compounds (1-6) was investigated using fourteen different solvents including polar, non-polar organic solvents. Only compound 1 solidified toluene. Characterization of compounds (1-6) was done using spectroscopic methods, HRESI-MS, FTIR, 1H- and 13C-NMR. The morphology of toluene organogel (as xerogel) was determined through scanning electron microscopy (SEM).
Databáze: OpenAIRE
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