Temperature dependent kinetics of the reaction OH + CF3CH2CF3

Autor:	Nancy L. Garland, H. H. Nelson
Rok vydání:	1996
Předmět:	Reaction rate constant Impurity Chemistry Kinetics General Physics and Astronomy Thermodynamics Physical and Theoretical Chemistry
Zdroj:	Chemical Physics Letters. 248:296-300
ISSN:	0009-2614
Popis:	We have re-examined the kinetics of the reaction of OH with CF 3 CH 2 CF 3 (FC 236fa) between 281 and 337 K using highly purified reactant. After accounting for the contribution to the measured rate of all measured impurities, we derive a room temperature rate constant k = (4.15 ± 0.33) × 10 −16 cm 3 s −1 , a factor of two smaller than our earlier report [J. Geophys. Res. 98 (1993) 23, 107] and in general agreement with other recent measurements.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::afa2959c7a79b6b9091aa69b21c4f5d7 https://doi.org/10.1016/0009-2614(95)01288-5 Zobrazit plný text záznamu Full Text from ScienceDirect