Ru-Catalyzed Hydrogenolysis of Chiral Allylic and Propargylic Cyclic Carbonates: Synthesis of Optically Active (E)-Allylic and Allenic Alcohols

Autor:	Seung-Hyun Yoon, Ho Sik Rho, Suk-Ku Kang, Pil-Su Ho, Dae-Yeun Kim
Rok vydání:	1996
Předmět:	Allylic rearrangement chemistry.chemical_compound Hydrogenolysis Chemistry organic chemicals Reductive cleavage Organic Chemistry Ammonium formate food and beverages Organic chemistry Regioselectivity Optically active Catalysis
Zdroj:	Synthetic Communications. 26:1485-1492
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919608003514
Popis:	RuH2(PPh3)4-catalyzed reductive cleavage reactions of chiral allylic cyclic carbonates with ammonium formate afforded optically active (E)-allylic alcohols with excellent regioselectivity. Alternatively, hydrogenolysis of propargylic cyclic carbonates in the presence of RuH2(PPh3)4 catalyst afforded allenic alcohols as a sole products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af9b954dd293916c90c5d07e31252505 https://doi.org/10.1080/00397919608003514 Zobrazit plný text záznamu