A direct route to medium and large cyclic amines from aminoalkenes

Autor:	Dilek Saylik, W. Roy Jackson, Eva M. Campi, David J. Bergmann, Antonio F. Patti
Rok vydání:	1999
Předmět:	Direct route Ligand Chemistry Organic Chemistry Drug Discovery Organic chemistry Regioselectivity Ring (chemistry) Biochemistry Hydroformylation Cyclic amines
Zdroj:	Tetrahedron Letters. 40:5597-5600
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(99)01020-5
Popis:	Rhodium-catalysed reactions of aminoalkenes with H 2 /CO give cyclic amines with a range of medium and large ring sizes in yields up to 85%. High regioselectivity for non-branched products can be obtained when BIPHEPHOS is used as a ligand in the hydroformylation reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af834d6b132788e3aa30175f64ba239a https://doi.org/10.1016/s0040-4039(99)01020-5 Zobrazit plný text záznamu Full Text from ScienceDirect