Synthesis of isomerically pure δ-chloro-γ-vinylketones

Autor:	A. Sh. Sunagatullina, Vladimir V. Zorin, R. N. Shakhmaev, R. M. Alieva
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Krapcho decarboxylation Organic chemistry General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences
Zdroj:	Russian Journal of General Chemistry. 87:2472-2476
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363217100310
Popis:	An efficient method for the synthesis of isomerically pure δ-chloro-γ-vinylketones was developed on the basis of monoalkylation of β-ketoesters with the individual isomers of 1,3-dichloropropene and the subsequent decarbalkoxylation of the resulting chlorovinyl derivatives under optimized Krapcho decarboxylation conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af6d4a4124e78776791aa8e5e2d6c015 https://doi.org/10.1134/s1070363217100310 Zobrazit plný text záznamu Plný text ve formátu PDF