3-Hydroxy-3-N-propyl-1-(4-sulphonamidophenyl) Triazene: A New Reagent for Spectrophotometric Determination of Nickel (II)

Autor:	Rekha Dashora, Saba Khan, Rehana Khanam
Rok vydání:	2014
Předmět:	Inorganic chemistry chemistry.chemical_element General Chemistry Food chemistry Molar absorptivity Biochemistry chemistry.chemical_compound Nickel chemistry GEOBASE FLUIDEX Reagent Drug Discovery Theoretical chemistry Environmental Chemistry Triazene
Zdroj:	Oriental Journal of Chemistry. 30:837-841
ISSN:	2231-5039 0970-020X
Popis:	Hydroxy-3-n-propyl-1-(4-sulphonamidophenyl)triazene has been used for spectrophotometric determination of Nickel(II) at 400 nm, keeping the pH between 6.9 to 7.3. The Beer's law is obeyed in the range 1x10-5 to 6x 10-5 M. The molar absorptivity and Sandell's sensitivity values are 6743 dm 3 mol -1 cm -1 and 8.61 ng cm -2 , respectively. The Nickel (II) has been determined successfully even in presence of upto 100 ppm of various interfering cations and anions. The reagent forms complex with iron at ratio of 1:2. The composition of complex was determined by Job's method and Mole ratio method of Yoe and Jones. The value of log ² found from two different methods were 9.57 and 9.53 respectively.
Databáze:	OpenAIRE
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