Baeyer-Villiger oxidation of bicyclic ketones by Cylindrocarpon destructans ATCC 11011

Autor:	Herfried Griengl, Kurt Faber, K. Königsberger, Gerhart Braunegg
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Cylindrocarpon destructans Ketone Bicyclic molecule Stereochemistry Chemistry Substrate (chemistry) Bioengineering General Medicine Applied Microbiology and Biotechnology Baeyer–Villiger oxidation Biotransformation Whole cell Biotechnology
Zdroj:	Biotechnology Letters. 12:509-514
ISSN:	1573-6776 0141-5492
DOI:	10.1007/bf01086344
Popis:	Baeyer-Villiger oxidation of bicyclic ketones1a,1b and4 using whole cell suspensions of the fungusCylindrocarpon destructans was found to proceed quantitatively and in case of substrate (±)-1b a moderate enantioselectivity was observed leading to (1S,6R)-1b and (1R,6S)-2b with 28% and 27% e.e., respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af5a6427c862511a5c4b0acd0c6a1fe0 https://doi.org/10.1007/bf01086344 Zobrazit plný text záznamu Full text from SpringerLink