Preparation of 4,7-Dihetaryl-1,2,5-oxadiazolo[3,4-c]pyridines as Red Fluorescent Materials

Autor: Katsumi Nishi-I, Tsuyoshi Sawada, Shuntaro Mataka, Thies Thiemann, Yoshio Kosugi, Hideki Gorohmaru, Kazufumi Takahashi, Naoko Ochi
Rok vydání: 2002
Předmět:
Zdroj: HETEROCYCLES. 56:421
ISSN: 0385-5414
DOI: 10.3987/com-01-s(k)64
Popis: A series of 1,2,5-oxadiazolo[3,4-c]pyridines (6, 7, 8 and 10) with thiophene, furan, and benzothiophene rings at the 4 and 7 positions were prepared, in quest of a red fluorescent material useful in OLED devices. Compound(6, 7, 8 and 10) emit fluorescence of orange to red color in solution and in the solid state. 6-Cyano derivatives (6) show a higher quantum yield than the corresponding esters (7), the phenyl derivative (8), and the unsubstituted compound (10). Red EL light at λ = 680 nm was obtained in an OLED device when 4,7-bis(5-phenylthien-2-yl) ester (7h) was used as a dopant emitter.
Databáze: OpenAIRE