Synthesis and structure of bis(tetraphenylantimony) malonate

Autor:	V. V. Zhidkov, I. N. Zubakina, I. V. Egorova, N. A. Rodionova
Rok vydání:	2020
Předmět:	010405 organic chemistry Ligand Coordination number chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound Malonate Antimony chemistry Octahedron Bromide Carboxylate Coordination geometry
Zdroj:	Russian Chemical Bulletin. 69:1279-1283
ISSN:	1573-9171 1066-5285
Popis:	Bis(tetraphenylantimony) malonate was synthesized by the reaction of tetraphenylantimony bromide with silver malonate (the molar ratio was 2:1) in toluene. According to the X-ray diffraction data, the tridentate carboxylate ligand is a chelate. The coordination number of the Sb(1) atom involved in a contact with the carbonyl oxygen atom increases to six (Sb(1)—O(1), 2.199(7) A; Sb(1)—O(3), 2.362(7) A). Another antimony atom remains five-coordinate (Sb(2)—O(4), 2.304(7) A). The antimony atoms Sb(1) and Sb(2) have distorted octahedral and trigonal-bipyramidal coordination geometry, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af51ff7d0443b4ef9826a86a99f2f8e0 https://doi.org/10.1007/s11172-020-2898-0 Zobrazit plný text záznamu Full text from SpringerLink