An angle resolved photoemission determination of the coordination of CO on the ZnO(0001) surface

Autor:	K. L. D'Amico, M. J. Sayers, Michael Trenary, Edward I. Solomon, N. D. Shinn, Michael R. McClellan, F. R. McFeely
Rok vydání:	1981
Předmět:	Chemistry Photoemission spectroscopy Coordination number Binding energy Analytical chemistry General Physics and Astronomy medicine.disease_cause Electron spectroscopy X-ray photoelectron spectroscopy Chemisorption medicine Physical and Theoretical Chemistry Spectroscopy Ultraviolet
Zdroj:	The Journal of Chemical Physics. 74:4726-4731
ISSN:	1089-7690 0021-9606
Popis:	Angle resolved ultraviolet photoemission spectroscopy employing polarized He ii resonance radiation has been used to determine the bonding geometry of CO to ZnO(0001) at 80 K. Bound CO molecules are oriented perpendicular to the zinc‐terminated surface forming a linear Zn–C–O complex. This result, along with earlier work on the ZnO(1010) surface, is explained by a concise and coherent model for CO chemisorption on ZnO surfaces. The role of defect sites for CO chemisorption is considered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af4d156f086afd98980498eb8d743df5 https://doi.org/10.1063/1.441618 Zobrazit plný text záznamu