Synthesis and Characterization of [(NHC)Ni(styrene)2] Complexes: Isolation of Monocarbene Nickel Complexes and Benchmarking of %VBur in (NHC)Ni-π Systems
| Autor: | Ryan T. VanderLinden, Janis Louie, Stephanie Felten, Sarah F. Marshall, Alisa J. Groom, Ryan M. Stolley |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Organic Chemistry chemistry.chemical_element Salt (chemistry) 010402 general chemistry 01 natural sciences 0104 chemical sciences Styrene Characterization (materials science) Inorganic Chemistry chemistry.chemical_compound Nickel Deprotonation chemistry Polymer chemistry Physical and Theoretical Chemistry |
| Zdroj: | Organometallics. 37:3687-3697 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.8b00394 |
| Popis: | The investigation of the stereoelectronic influence of N-aryl substituted NHC ligands on Ni(0) is reported. The structural analysis of a family of [(NHC)Ni(styrene)2] complexes are correlated to known literature parameters (TEP and %VBur). The analysis involved NMR spectroscopic techniques and X-ray crystallography analysis of the isolated [(NHC)Ni(styrene)2] complexes. The synthesis and characterization of this user-friendly and easy accessible Ni(0) precatalysts can be realized in a two-step synthesis starting from deprotonation of the imidazolium salt followed by direct coordination onto nickel in the presence of excess styrene. |
| Databáze: | OpenAIRE |
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