Synthesis of 5-acetyl derivatives of alkyl 2-furoates and 3-(2-furyl)acrylates

Autor:	K. V. Kuticheva, M. L. Petrov, L. M. Pevzner
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Sodium chemistry.chemical_element General Chemistry chemistry.chemical_compound Acetic anhydride Acetoxy group chemistry Acetylation Reagent Chlorine Organic chemistry Magnesium perchlorate Alkyl
Zdroj:	Russian Journal of General Chemistry. 85:424-427
ISSN:	1608-3350 1070-3632
Popis:	Methyl 5-acetyl-2-furoate has been prepared via oxidation of 5-(1-hydroxyethyl)-2-furoate with the Jones reagent. In turn, the starting compound has been synthesized via sequential chloroethylation of ethyl 2-furoate, substitution of chlorine with acetoxy group, and methanolysis of the acetate in presence of sodium methylate. The vinylog 2-furoate has been obtained as the major product via acetylation of ethyl 3-(2-furyl)-acrylate with acetic anhydride in the presence of magnesium perchlorate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af426adc24308b1e515ffab574f5e3f6 https://doi.org/10.1134/s1070363215020127 Zobrazit plný text záznamu Plný text ve formátu PDF