Photo induced trans→cis isomerism studies of heteroleptic iridium complex with 8-quinolinol-5-phenylazo ligand: Photophysical and electrochemical studies and it's theoretical investigations
| Autor: | Amit Maity, Kajal Krishna Rajak |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Photoisomerization
010405 organic chemistry Ligand Organic Chemistry chemistry.chemical_element 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Azobenzene chemistry Moiety Iridium Isomerization Spectroscopy Cis–trans isomerism Derivative (chemistry) |
| Zdroj: | Journal of Molecular Structure. 1181:38-47 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2018.12.060 |
| Popis: | Free rotating azo type ligand in different types of metal complexes give trans-cis isomerism in presence of photon irradiation by UV light. For this connection one new iridium complex has been synthesized with 8-hydroxyquinoline-5-phenylazo ligand in which the azo part of the ligand is free from coordination with metal centre. UV light irradiation of the Ir complex with this type of 8-hydroxyquinoline-5-arylazo ligand at room temperature promotes the trans→cis photoisomerization of the N N bond with formation of a cis-isomer. The complex is characterised by single X-ray diffractometry, IR, mass and 1HNMR spectroscopy method. Here we report on the synthesis, the electrochemical properties and the photophysical characterization of donor-acceptor azobenzene derivative that possess 8-quinolinol group connected to a benzene moiety and it's cis-trans isomerisation reaction and stability of the isomers. Thoroughly DFT and TD-DFT calculations are performed to correlate experimental and theoretical interpretation. |
| Databáze: | OpenAIRE |
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