Synthesis and characterization of transition metal dithiocarbamate derivatives of 1-aminoadamantane: Crystal structure of (N-adamantyldithiocarbamato)nickel(II)

Autor:	Vahid Amani, Akram Ashouri, Katayoun Marjani, Azim Ziyaei Halimehjani
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Denticity Double bond Ligand Inorganic chemistry chemistry.chemical_element Crystal structure Inorganic Chemistry Nickel Crystallography Transition metal chemistry Materials Chemistry Moiety Physical and Theoretical Chemistry Dithiocarbamate
Zdroj:	Inorganica Chimica Acta. 373:282-285
ISSN:	0020-1693
DOI:	10.1016/j.ica.2011.02.089
Popis:	Four bis(N-adamantyldithiocarbamato)metal(II) complexes [M(S2CNHC10H15)2] (M = Ni, Zn, Cd, and Hg) were prepared by metathesis of the corresponding potassium salt, K[S2CNHC10H15]. Characterization of the prepared complexes shown that the presence of only one band in the region 1000 cm−1 in IR spectra can be attributed to a completely symmetrical bonding of the dithiocarbamate ligand, acting in a symmetrical bidentate mode. Also the short thioureide C–N distance in X-ray analysis of Ni complex confirm the delocalization of the π electrons over the S2CN moiety and strong double bond character.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af148d63aa4c97237362c8024ccb51d9 https://doi.org/10.1016/j.ica.2011.02.089 Zobrazit plný text záznamu Full Text from ScienceDirect