Three transition metal complexes based on nicotinate: Synthesis, structure and adsorption properties
| Autor: | Xiao Xin Han, Feng Ying Bai, Bing Li, Ying Sun, Lixian Sun, Na Zhang, Yong Heng Xing, Yu Xin |
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| Rok vydání: | 2020 |
| Předmět: |
Thermogravimetric analysis
010405 organic chemistry Hydrogen bond Infrared Chemistry Organic Chemistry Supramolecular chemistry Crystal structure 010402 general chemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Crystallography Adsorption Transition metal Spectroscopy Powder diffraction |
| Zdroj: | Journal of Molecular Structure. 1205:127656 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2019.127656 |
| Popis: | This work designed and synthesized three complexes by the hydrothermal synthetic method, They are [Zn (nic)2(H2O)2]n (1), [Ni2(nic)4 (μ2-H2O)]n (2), [Co2(nic)4 (μ2-H2O)]n (3), respectively. The complexes were characterized by elemental analysis, infrared spectrum, ultraviolet spectrum, thermogravimetric analysis and X-ray powder diffraction etc. The crystal structures of complexes 1–3 were measured by X-ray single crystal diffraction. Complex 1 formed a 3D supramolecular structure through hydrogen bonds, and complexes 2–3 formed 3D network structures with coordination bonds. The adsorption properties of complexes 1–3 on the coomass bright blue G250 (CBB) were tested, meanwhile, whose adsorption kinetics were also studied. |
| Databáze: | OpenAIRE |
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