Interseparation of Platinum Metals in Concentrated Solution by Gel Permeation Chromatography
| Autor: | B. Limoni-Relis, G. Schmuckler |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Elution Process Chemistry and Technology General Chemical Engineering Inorganic chemistry Salt (chemistry) Halide chemistry.chemical_element Filtration and Separation General Chemistry Permeation Gel permeation chromatography chemistry.chemical_compound Metal halides chemistry Platinum |
| Zdroj: | Separation Science and Technology. 30:337-346 |
| ISSN: | 1520-5754 0149-6395 |
| DOI: | 10.1080/01496399508013875 |
| Popis: | The chromatographic interseparation of the anionic halide complexes of platinum metals in concentrated acidic solutions by certain polydextran gels as the separating medium and aqueous electrolyte solutions as eluents is described. The dextran groups of highly crosslinked gels of this type interact selectively with platinum halides via H-bonding, and these platinum group metal halides can then be easily eluted with aqueous salt or acid solutions. The separations are sharp and rapid and can be carried out at room temperature. Base metal halides do not form H-bonds with the gels and are therefore eluted from the column before the platinum metals. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|