Monoammonium Bis(D-penicillaminato-S)aurate(I) 3.667-Hydrate

Autor:	Colin J. L. Lock, Zhixian Wang, Daren J. LeBlanc, James F. Britten, H. E. Howard-Lock
Rok vydání:	1997
Předmět:	Ligand Inorganic chemistry General Medicine Crystal structure Dihedral angle General Biochemistry Genetics and Molecular Biology Bond length chemistry.chemical_compound Crystallography chemistry Molecule Amine gas treating Carboxylate Hydrate
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 53:1763-1765
ISSN:	0108-2701
DOI:	10.1107/s0108270197009724
Popis:	The anion of the title compound, (NH 4 )[Au(C 5 H 10 NO 2 S) 2 ].3.667H 2 O, has roughly linear coordination of the Au atom to the S atoms of the ligands [Au-S 2.2900(13)A and S-Au-S 178.47(7)°]. The C-S...S-C torsion angle is 29.3 (2)°. The packing arrangement is determined by short Au...Au contacts [3.221(1)A] as well as hydrogen-bonding interactions between ligand carboxylate and amine functional groups, the ammonium counter-cation and water molecules of hydration. Bond lengths and angles are normal.
Databáze:	OpenAIRE
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