Double layer effect on the electrode kinetic reduction of Pu(IV) carbonate complexes in aqueous solution

Autor: Sergio Casadio, Franco Orlandini
Rok vydání: 1972
Předmět:
Zdroj: Journal of Inorganic and Nuclear Chemistry. 34:3845-3849
ISSN: 0022-1902
DOI: 10.1016/0022-1902(72)80032-0
Popis: The influence of double layer structure on the kinetic parameters for the Pu(IV) + e = Pu(III) charge transfer in carbonate media is consistent with anionic depolarizing species associated with supporting cations (ion pairs) in the increasing order Na + , K + and Cs + , whose specific adsorption at the mercury electrode, increasing in the same way, could explain the observed variations in transfer coefficient with the nature of the supporting cation.
Databáze: OpenAIRE