Double layer effect on the electrode kinetic reduction of Pu(IV) carbonate complexes in aqueous solution
Autor: | Sergio Casadio, Franco Orlandini |
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Rok vydání: | 1972 |
Předmět: | |
Zdroj: | Journal of Inorganic and Nuclear Chemistry. 34:3845-3849 |
ISSN: | 0022-1902 |
DOI: | 10.1016/0022-1902(72)80032-0 |
Popis: | The influence of double layer structure on the kinetic parameters for the Pu(IV) + e = Pu(III) charge transfer in carbonate media is consistent with anionic depolarizing species associated with supporting cations (ion pairs) in the increasing order Na + , K + and Cs + , whose specific adsorption at the mercury electrode, increasing in the same way, could explain the observed variations in transfer coefficient with the nature of the supporting cation. |
Databáze: | OpenAIRE |
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