Vapor–Liquid Equilibrium Measurements for Carbon Dioxide + Cyclohexene + Squalane at High Pressures Using a Synthetic Method
| Autor: | Osvaldo Chiavone-Filho, Fedra A. V. Ferreira, Thales Cainã dos Santos Barbalho, Humberto Neves Maia de Oliveira |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Equation of state Ternary numeral system General Chemical Engineering Cyclohexene Thermodynamics 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology chemistry.chemical_compound Hydrocarbon 020401 chemical engineering chemistry Squalane Phase (matter) Organic chemistry Vapor–liquid equilibrium Binary system 0204 chemical engineering 0210 nano-technology |
| Zdroj: | Journal of Chemical & Engineering Data. 62:1456-1463 |
| ISSN: | 1520-5134 0021-9568 |
| DOI: | 10.1021/acs.jced.6b01018 |
| Popis: | Growing interest in the study of production conditions in the presalt led to the need to study complex systems at high pressures and temperatures, such as up to 70 MPa and up to 393 K. The aim of this work is to obtain vapor–liquid equilibrium data at high pressures and temperatures for hydrocarbon systems with carbon dioxide (CO2). To obtain these data, an experimental setup and procedure using a synthetic cell were designed. Experimental data of the binary system CO2 + cyclohexene (C6H10) and CO2 + squalane (C30H62) over a range of temperature between 303 and 398 K and the ternary system CO2 + C6H10 + C30H62 at various temperatures (318–393 K) and compositions are reported. It is noteworthy that the reported measurements in this work were not studied in the literature, and experimental data may contribute to industrial and scientific interests. The phase behavior of the system was also described using the Soave–Redlich–Kwong equation of state together with Mathias–Copeman alpha function. Interaction par... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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