Synthesis of poly-yne polymer containing platinum and silicon atoms in the main chain by oxidative coupling and its reactions with transition-metal carbonyl complexes

Autor:	Kenkichi Sonogashira, Toshihiro Matsumoto, Kyo Shiina, Sonae Kotani
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Chemistry Alkyne chemistry.chemical_element General Chemistry Photochemistry Inorganic Chemistry NMR spectra database chemistry.chemical_compound Monomer Transition metal Polymer chemistry Proton NMR Polysilane Oxidative coupling of methane Platinum
Zdroj:	Applied Organometallic Chemistry. 7:613-621
ISSN:	1099-0739 0268-2605
DOI:	10.1002/aoc.590070804
Popis:	The platinum poly-yne polymer, [CCSiMe2CCPt(PBu3)2CCSiMe2CC]n (2), was synthesized by the oxidative coupling of a silicon–platinum monomer, trans-(PBu3)2Pt(CCSiMe2–CCH)2 (1). The reaction of platinum poly-yne polymer 2 with dicobaltoctacarbonyl gave μ-coordinated complexes, {[CCSiMe2CCPt(PBu3)2CCSiMe2CC] [Co2(Co)6]2}n (4). the electric conductivity of iodine adducts of the polymer complexes 4 was 3.0×10−5 S cm−1. As an aid to spectroscopic characterization of the polymer complex 4, a model complex, {trans-[(PBu3)2Pt(CCSiMe2CCH)2]} {[Co2(CO)6]2} (3), was also prepared by the reaction of 1 with dicobaltocatacarbonyl. Selective coordination of Co2(CO)6 groups to SiMe2CC CCSi(Me)2 Moieties and coordinative inertness of the PtCC moieties were confirmed by comparison of the NMR spectra of 3 with those of 4. All new compounds have been characterized by analytical and spectral analysis (IR, 1H NMR).
Databáze:	OpenAIRE
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