Revisiting [Mn(CO)3(η5-nido-7,8-C2B9H11)]-, the Dicarbollide Analogue of [(η5-C5H5)Mn(CO)3]: Reactivity Studies Leading to Boron Atom Functionalization

Autor:	Mitsuhiro Hata, F. Gordon A. Stone, Xiu Lian Lu, Jason A. Kautz, Thomas D. McGrath
Rok vydání:	2004
Předmět:	Inorganic Chemistry Stereochemistry Chemistry Reagent Organic Chemistry Surface modification Reactivity (chemistry) Physical and Theoretical Chemistry Boron atom Medicinal chemistry
Zdroj:	Organometallics. 23:3590-3602
ISSN:	1520-6041 0276-7333
Popis:	Treatment of Na2[7,8-R2-nido-7,8-C2B9H9] (R = H, Me) with the reagent [Mn(NCMe)3(CO)3][PF6] affords the anions [3,3,3-(CO)3-1,2-R2-closo-3,1,2-MnC2B9H9]-, typically isolated as Cs+ or [N(PPh3)2]+ s...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ae3358e2134c7c3000f7460ae2d29f71 https://doi.org/10.1021/om049822l Zobrazit plný text záznamu