Binuclear manganese complexes as catalysts in the selective and efficient oxidation of sulfides to sulfones

Autor:	Wen-Shan Li, Jason A. Smith, Derek H. R. Barton
Rok vydání:	1998
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Drug Discovery Polymer chemistry Periodic acid chemistry.chemical_element Manganese Highly selective Biochemistry Catalysis
Zdroj:	Tetrahedron Letters. 39:7055-7058
ISSN:	0040-4039
Popis:	The binuclear MnIVMnIV manganese complex 1 catalyzes the periodic acid oxidation of sulfides to sulfones under mild conditions. The reaction was found to be highly selective giving almost quantitative yields of the sulfones even in the presence other easily oxidized groups. Only amines were found to hinder the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ae2fec0d874732c4f186942fdcb76bfb https://doi.org/10.1016/s0040-4039(98)01518-4 Zobrazit plný text záznamu Full Text from ScienceDirect