Oxidation of cyclohexane—A significant impact of stainless steel reactor wall

Autor:	Fengyu Zhao, Hongjun Wang, Haiyang Cheng, Jianmin Hao, Shuxia Cai
Rok vydání:	2007
Předmět:	Alkane chemistry.chemical_classification Cyclohexane Process Chemistry and Technology Alloy Inorganic chemistry Cyclohexanol Cyclohexanone engineering.material Heterogeneous catalysis Catalysis chemistry.chemical_compound Cycloalkane chemistry engineering Physical and Theoretical Chemistry
Zdroj:	Journal of Molecular Catalysis A: Chemical. 271:42-45
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2007.02.031
Popis:	The selective oxidation of cyclohexane to cyclohexanol and cyclohexanone is an important chemical process and it has been paid more attentions recently. In the present work, the stainless steel reactor wall was found to influence the selective oxidation of cyclohexane very significantly, and a quasi-crystalline Ti45Zr35Ni17Cu3 alloy with the similar compositions as the reactor wall was used as a catalyst for the cyclohexane oxidation, as expected, a higher activity was obtained with it. The present results open up a new avenue for developing new catalyst for alkane oxidation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ae21ce89857f809e8ab6754ba12045be https://doi.org/10.1016/j.molcata.2007.02.031 Zobrazit plný text záznamu Full Text from ScienceDirect