Advances in Cu2ZnSnSe4 solar cell performance using 2SSS processing
Autor: | Y. Wang, Christos Ferekides, Don L. Morel |
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Rok vydání: | 2016 |
Předmět: |
010302 applied physics
Materials science Fabrication business.industry Band gap Nanotechnology 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences law.invention chemistry.chemical_compound symbols.namesake chemistry law 0103 physical sciences Solar cell symbols Optoelectronics CZTS 0210 nano-technology business Raman spectroscopy |
Zdroj: | 2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC). |
DOI: | 10.1109/pvsc.2016.7750032 |
Popis: | We have developed an all-solid-state two-step process(2SSS) for fabrication of Cu 2 ZnSnSe 4 (CZTS) devices. Raman spectra are used to determine and control secondary phases and formation of excess MoSe 2 at the CZTS/Mo interface due to over selenization. While processing at temperatures above 450 C decreases ZnSe and CuSe phases, a temperature driven interface recombination mechanism reduces Jsc and FF resulting in device efficiencies of 3%. Voc's, however are in the range 0.40–0.43 volts which are the same as for comparable band gap CIS and among the highest reported for CZTS. |
Databáze: | OpenAIRE |
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