Advances in Cu2ZnSnSe4 solar cell performance using 2SSS processing

Autor: Y. Wang, Christos Ferekides, Don L. Morel
Rok vydání: 2016
Předmět:
Zdroj: 2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC).
DOI: 10.1109/pvsc.2016.7750032
Popis: We have developed an all-solid-state two-step process(2SSS) for fabrication of Cu 2 ZnSnSe 4 (CZTS) devices. Raman spectra are used to determine and control secondary phases and formation of excess MoSe 2 at the CZTS/Mo interface due to over selenization. While processing at temperatures above 450 C decreases ZnSe and CuSe phases, a temperature driven interface recombination mechanism reduces Jsc and FF resulting in device efficiencies of 3%. Voc's, however are in the range 0.40–0.43 volts which are the same as for comparable band gap CIS and among the highest reported for CZTS.
Databáze: OpenAIRE