SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAIMIDAZOLE(DIAQUA)-MANGANESE(II) TEREPHTHALATE

Autor:	Duan-Jun Xu, Yan Liu, Jiagen Liu
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Crystallography Ethanol chemistry Inorganic chemistry Materials Chemistry Infrared spectroscopy Imidazole chemistry.chemical_element Crystal structure Manganese Physical and Theoretical Chemistry Thermal analysis
Zdroj:	Journal of Coordination Chemistry. 54:175-181
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958970108027153
Popis:	The title complex, [Mn(C3H4N2)4(H2O)2]·(C8H4O4), was prepared by reaction of terephthalato (diaqua)manganese (II) with imidazole in ethanol/water solution. The complex crystallizes in space group C2/c with cell parameters a = 22.494(5), b = 7.741(2), c = 16.287(3)A, β = 120.94(3)°, Z = 4. The complex consists of complex Mn(II) cations and uncoordinated terephthalate anions; the latter link cations through an H-bonding network. Thermal analyses and IR spectra are discussed in terms of the formation of the complex.
Databáze:	OpenAIRE
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