Influence of the Lewis acid on the nucleophilic addition to β,β-disubstituted α-enones

Autor:	Lya Wartski, M Zervos
Rok vydání:	1986
Předmět:	Diketone Nucleophilic addition Chemistry Organic Chemistry Alkylation Biochemistry Catalysis chemistry.chemical_compound Drug Discovery Michael reaction Organic chemistry Lewis acids and bases Enone Carbanion
Zdroj:	Tetrahedron Letters. 27:2985-2988
ISSN:	0040-4039
Popis:	Lewis acids as BF3.Et2O, Ti(OiPr)4, ZnCl2 allow the Michael addition of lithiated aminonitrile 1 to β,β-disubstituted α-enones leading thus after carbonyl unmasking to the corresponding diketones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ade189c4af9f2b314550187096883427 https://doi.org/10.1016/s0040-4039(00)84697-3 Zobrazit plný text záznamu